Effect of Hydrogen on Kinetics of Oxidation of Hydrazine with Solution Acid

Madhu Shrimal

Abstract


The kinetics of oxidation of hydrazine by iodine in presence of excess iodide has been studied. The reaction is second order and hydrogen ion concentration reduces the rate .The reaction stoichiometry corresponds to the reaction as represented by eqn (1)

2 I2 + N2H4 4 I + N2 + 4H+ (1)

The Kinetic rate law (2) accounts for the proposed mechanism.

(2)


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