Co-Ordination Behavior of Amino Thiozole with Transition Metal Complexes

Abstract

The ambidentate behaviour of diazoles is well known - The substitution of an amino group makes the ligand more efficient coordination due to increase in one more binding site. In addition the substitution at 2 position makes the ligand more suitable to act as a chelating agent. Therefore it promoted us to study the coordination behavior of 2 amino-diazole towards some metals of the first transition reactions with other ligands such neutral ligands like pyridine, picoline etc will be. studies. Complexes of 2 amino diazoles with the first sow transition elements salts and the ligand in appropriate solvents. The solvents will be aried by standard method (36) the metal will be estimated by the usual procedure (36). Sulpher and halogens will be estimated by fusion method and nitrogen by kjeldahis method the complex prepared will be structurally investigated by infrared and electronic spectra.